Iron(II) hydrazinium sulfate
نویسندگان
چکیده
منابع مشابه
(Methoxycarbonyl)hydrazinium chloride monohydrate
In the title compound, C(2)H(7)N(2)O(2) (+)·Cl(-)·H(2)O, the non-H atoms of the cation are approximately coplanar. The organic cations, chloride ions and water mol-ecules are linked into a two-dimensional network parallel to the bc plane by N-H⋯O, N-H⋯Cl and O-H⋯Cl hydrogen bonds.
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The proton spin-lattice relaxation time Tl (at 5.4, 10 and 15 MHz) and second moment M 2 (at 9.8 MHz) have been measured in hydrazinium Perchlorate (N 2 H 5 C10 4 ) . The temperature dependence of T, shows two minima. The low temperature T, minimum has been explained in terms of N H 3 reorientation about the N N axis while the high temperature minimum is attributed to the exchange of protons wi...
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In the cation of the title compound, C(8)H(10)ClN(4)O(+)·Cl(-)·H(2)O, the guanidinium group is planar (maximum deviation = 0.0001 Å) and nearly perpendicular to carboxamide group, making a dihedral angle of 87.0 (3)°. The N atoms of the guanidine fragment have a planar trigonal configuration and the N atom of the carboxamide group adopts a pyramidal configuration. In the crystal structure, inte...
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In the anion of the title salt hydrate, H5N2+·C7H5N2O4-·2H2O, the carboxyl-ate and nitro groups lie out of the plane of the benzene ring to which they are bound [dihedral angles = 18.80 (10) and 8.04 (9)°, respectively], and as these groups are conrotatory, the dihedral angle between them is 26.73 (15)°. An intra-molecular amino-N-H⋯O(carboxyl-ate) hydrogen bond is noted. The main feature of th...
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In the crystal structure of the title salt, 3C(5)H(6)NO(+)·HSO(4) (-)·SO(4) (2-)·H(2)O, the hydrogen sulfate ion is linked to the sulfate ion by an O-H⋯O hydrogen bond. The hydrogen sulfate-sulfate anion is a hydrogen-bond acceptor for the three independent cations and the uncoordinated water mol-ecule, the hydrogen-bonding inter-actions giving rise to a three-dimensional hydrogen-bonded networ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2007
ISSN: 1600-5368
DOI: 10.1107/s1600536806056509